Precious Metal Nanoparticles: High-Tech Made from Conductive Ink
Ink plays a key role in producing printed conductive features of this kind. It consists of tiny particles of precious metals – such as silver or gold – ranging in size from 10 to 100 nanometers. “The electrical conductivity of the structures we produce varies depending on which precious metal particles are incorporated into the ink. For example, silver has the highest electrical conductivity of all precious metals. The intended application of the printed electronics and the desired properties of the printed product determine which substrate should be used, its surface characteristics, the appropriate printing process, and the choice of ink – and thus the conductivity of the printed components,” the researcher notes.
While certain inks are supplied by specialized partners, Fraunhofer ENAS develops unique inks specifically for the production of hydrogen-based systems. These contain nanoparticles of either the precious metal platinum or iridium dioxide and are used in the production of catalyst-coated membranes (CCMs) and membrane electrode assemblies (MEAs) for use in water electrolyzers and fuel cells. “This gives us a unique selling proposition as an institution. The inks we have developed are unparalleled and are based on a globally unique formula,” emphasizes Ralf Zichner. Their specific composition means that they can be printed directly and contactlessly onto a membrane, thereby functionalizing it.
For this, the researchers use specialized printing techniques such as inkjet printing. This creates the desired printed pattern in just a few minutes based on a predefined design template – with no contact whatsoever and with pinpoint accuracy. Print speeds of up to 10 meters per minute are achieved at a droplet ejection rate of 20,000 fine droplets per second. At this rate, an industrial inkjet print head with, for example, 1,280 nozzles ejects 25.6 million droplets per second, enabling extremely fast print speeds.
After printing, the structures produced in this way – for example, those made of silver – are not initially electrically conductive. “After printing, the metallic nanoparticles are arranged side by side. It is only the subsequent drying process – also known as sintering – that causes the particles to fuse together through heating, giving them their final, conductive form.”
In this way, Fraunhofer ENAS is able to produce structures with ultra-thin layer thicknesses ranging from 250 nanometers to 30 micrometers, which is why the components produced like this are also referred to as thin-film electronics. “A comparison illustrates just how tiny the printed electronics we can create actually are: For example, a tiny bacterium is 300 nanometers in size, while a single human hair has a diameter of about 50 micrometers," the researcher points out.
The scientist is convinced that conductive functional structures on this scale will play a decisive role in shaping our future. This is because increasingly compact high-tech innovations rely on small, lightweight circuits that must adapt flexibly to the smallest of installation spaces. Printed electronics are a key driver that will significantly influence this development in the coming years.
Research and Development Services for Printed Functionalities
Fraunhofer ENAS is your partner for research and development services in the field of printed, flexible, and hybrid functionalities. Using state-of-the-art printing technologies, we can create electrically conductive functional structures and complex elements on virtually any object or surface – regardless of geometry or contour.
Our portfolio of services includes custom electronic component design, selection of the ideal ink, determination of the optimal printing process, customized substrate pre-treatment, optimized post-treatment of printed layers, and characterization of printed functional layers and designs. That is how we transform your visions into tailored solutions for your unique challenges.
Our offering in detail:
- Adaptation of printing technologies, including the selection of materials and process technologies for producing printed solutions
- Analysis of ink printability using specific printing technologies
- Printing tests, such as
- Cleanroom-free, continuous roll-to-roll, and sheet-fed processes | Screen printing, inkjet printing, and dispensing
- Printing onto 3D objects using inkjet printing and dispensing processes
- Transfer of knowledge relating to existing printing technologies for functional printing (web- and sheet-fed printing), including their fields of application and implementation
- Design of printed components and production of demonstrators, such as
- Catalyst-coated membranes (CCMs)/membrane electrode assemblies (MEAs), circuit traces, electrodes, antennas, batteries, sensors, resistors, transistors, capacitors, diodes, or protective coatings
- Development of product and circuit designs, including the prototyping of printed, flexible, and hybrid electronics
- Characterization of printed functional layers with regard to their surface and electrical properties, for example by means of
- Micro-X-ray fluorescence (µXRF), scanning electron microscopy (SEM) analysis, tactile profilometry, 4-point measurement, measurement of current-carrying capacity or high-frequency properties
- Characterization of printed components, such as
- Catalyst-coated membranes (CCMs)/membrane electrode assemblies (MEAs), circuit traces, electrodes, antennas, batteries, or resistors
- Placement of SMDs (surface-mounted devices) on printed circuit boards
Would you like to learn more about Fraunhofer ENAS’s printing technologies and their potential to drive high-impact innovation? If so, we look forward to hearing from you.